Cv=Cp-nR

pV is proportional to absolute temperature

Molar entropy does not depend on pressure

the enthalpy does not depend on pressure

Molar entropy always increases with temprerature

q+w=TΔS

ΔU=w but only for perfect gas

ΔU=w

ΔT=0

ΔU=ΔH+Δ(pV) but only for perfect gas

is equal to TΔcSo+ΔcGo

is defined at standard pressure

is the the heat effect of reaction of combustion of 1 mole of a compound in air at standard pressure

doesn’t depend on temperature

none from above

is equal to (C_v razy delta T)/T

is equal to zero

is equal to -delta(pV)/T

is equal to delta(pV)/T

The transition entropy is delta H=T delta trans S

The heat capacity shows a discontinuity

thermal expresion coefficient shows a discontinuity

Entropy shows a discontinuity

Entropy changes in continous way

doesn’t depend on pressure

at the triple point of a substance is equal for solid, liquid and vapor

can be defined as (dG/dξ)T

has a minimum at the critical point

always increases with temperature

is equal to Rlnx in system (henry's law)

is equal to -RTlnx in system (raoult's law)

is equal to RTlnx in system (henry's law)

is 0 for perfect gases

is equal to -Rlnx in system (raoult's law)

does not depend on temperature

does not depend on the total volume of the reaction mixture

has a temperature dependence given by the Van’t Hoff law

depends on the molar fractions of reactants and products in the mixture

depends on the partial pressures in the reaction mixture